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Shape‐Shifting Molecules: Unveiling the Valence Tautomerism Phenomena in Bare Barbaralones

We report a state‐of‐the‐art spectroscopic study of an archetypical barbaralone, conclusively revealing the valence tautomerism phenomena for this bistable molecular system. The two distinct 1‐ and 5‐substituted valence tautomers have been isolated in a supersonic expansion for the first time and su...

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Detalles Bibliográficos
Autores principales: Sanz‐Novo, Miguel, Mato, Mauro, León, Íker, Echavarren, Antonio M., Alonso, José L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9311078/
https://www.ncbi.nlm.nih.gov/pubmed/35165988
http://dx.doi.org/10.1002/anie.202117045