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Functionalization and Hydrogenation of Carbon Chains Derived from CO

Selective reactions that combine H(2), CO and organic electrophiles (aldehyde, ketones, isocyanide) to form hydrogenated C(3) and C(4) carbon chains are reported. These reactions proceed by CO homologation mediated by [W(CO)(6)] and an aluminum(I) reductant, followed by functionalization and hydroge...

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Detalles Bibliográficos
Autores principales: Batuecas, Maria, Kong, Richard Y., White, Andrew J. P., Crimmin, Mark R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9311202/
https://www.ncbi.nlm.nih.gov/pubmed/35225403
http://dx.doi.org/10.1002/anie.202202241