Electrochemically Driven Swinging of a Nitrobenzyl Pendant Arm in a Nickel Scorpionand Complex

A radical anion −NO(2) (.−) is formed upon an electrochemically reversible one‐electron reduction of the square‐planar Ni(II) complex of N‐nitrobenzylcyclam. The −NO(2) (.−) group goes to occupy an axial position of the metal ion, thus establishing a significant electronic interaction with the metal...

Descripción completa

Detalles Bibliográficos
Autores principales: Ciarrocchi, Carlo, Fabbrizzi, Luigi, Licchelli, Maurizio, Taglietti, Angelo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9311437/
https://www.ncbi.nlm.nih.gov/pubmed/35234313
http://dx.doi.org/10.1002/chem.202200462

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9311437/
https://www.ncbi.nlm.nih.gov/pubmed/35234313
http://dx.doi.org/10.1002/chem.202200462

Ejemplares similares