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Electrochemically Driven Swinging of a Nitrobenzyl Pendant Arm in a Nickel Scorpionand Complex
A radical anion −NO(2) (.−) is formed upon an electrochemically reversible one‐electron reduction of the square‐planar Ni(II) complex of N‐nitrobenzylcyclam. The −NO(2) (.−) group goes to occupy an axial position of the metal ion, thus establishing a significant electronic interaction with the metal...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9311437/ https://www.ncbi.nlm.nih.gov/pubmed/35234313 http://dx.doi.org/10.1002/chem.202200462 |