High‐Temperature Quantum Tunneling and Hydrogen Bonding Rearrangements Characterize the Solid‐Solid Phase Transitions in a Phosphonium‐Based Protic Ionic Liquid

We report the complex phase behavior of the glass forming protic ionic liquid (PIL) d3‐octylphosphonium bis(trifluoromethylsulfonyl)imide [C(8)H(17)PD(3)][NTf(2)] by means of solid‐state NMR spectroscopy. Combined line shape and spin relaxation studies of the deuterons in the PD(3) group of the octy...

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Detalles Bibliográficos
Autores principales: Khudozhitkov, Alexander E., Donoshita, Masaki, Stepanov, Alexander G., Philippi, Frederik, Rauber, Daniel, Hempelmann, Rolf, Kitagawa, Hiroshi, Kolokolov, Daniil I., Ludwig, Ralf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9311734/
https://www.ncbi.nlm.nih.gov/pubmed/35187737
http://dx.doi.org/10.1002/chem.202200257

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9311734/
https://www.ncbi.nlm.nih.gov/pubmed/35187737
http://dx.doi.org/10.1002/chem.202200257

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