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X‐ray Electron Density Study of the Chemical Bonding Origin of Glass Formation in Metal–Organic Frameworks

Glass‐forming metal–organic frameworks (MOFs) have novel applications, but the origin of their peculiar melting behavior is unclear. Here, we report synchrotron X‐ray diffraction electron densities of two zeolitic imidazolate frameworks (ZIFs), the glass‐forming Zn‐ZIF‐zni and the isostructural ther...

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Detalles Bibliográficos
Autores principales: Sarkar, Sounak, Grønbech, Thomas Bjørn Egede, Mamakhel, Aref, Bondesgaard, Martin, Sugimoto, Kunihisa, Nishibori, Eiji, Iversen, Bo Brummerstedt
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9313623/
https://www.ncbi.nlm.nih.gov/pubmed/35286738
http://dx.doi.org/10.1002/anie.202202742