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Olefin Metathesis Catalysts Generated In Situ from Molybdenum(VI)‐Oxo Complexes by Tuning Pendant Ligands

Tailored molybdenum(VI)‐oxo complexes of the form MoOCl(2)(OR)(2)(OEt(2)) catalyse olefin metathesis upon reaction with an organosilicon reducing agent at 70 °C, in the presence of olefins. While this reactivity parallels what has recently been observed for the corresponding classical heterogeneous...

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Detalles Bibliográficos
Autores principales: Nater, Darryl F., Kaul, Christoph J., Lätsch, Lukas, Tsurugi, Hayato, Mashima, Kazushi, Copéret, Christophe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9313794/
https://www.ncbi.nlm.nih.gov/pubmed/35234311
http://dx.doi.org/10.1002/chem.202200559