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Olefin Metathesis Catalysts Generated In Situ from Molybdenum(VI)‐Oxo Complexes by Tuning Pendant Ligands
Tailored molybdenum(VI)‐oxo complexes of the form MoOCl(2)(OR)(2)(OEt(2)) catalyse olefin metathesis upon reaction with an organosilicon reducing agent at 70 °C, in the presence of olefins. While this reactivity parallels what has recently been observed for the corresponding classical heterogeneous...
Autores principales: | Nater, Darryl F., Kaul, Christoph J., Lätsch, Lukas, Tsurugi, Hayato, Mashima, Kazushi, Copéret, Christophe |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9313794/ https://www.ncbi.nlm.nih.gov/pubmed/35234311 http://dx.doi.org/10.1002/chem.202200559 |
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