Carbodefluorination of fluoroalkyl ketones via a carbene-initiated rearrangement strategy

The C–F bond cleavage and C–C bond formation (i.e., carbodefluorination) of readily accessible (per)fluoroalkyl groups constitutes an atom-economical and efficient route to partially fluorinated compounds. However, the selective mono-carbodefluorination of trifluoromethyl (CF(3)) groups remains a ch...

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Detalles Bibliográficos
Autores principales: Li, Linxuan, Zhang, Xinyu, Ning, Yongquan, Zhang, Xiaolong, Liu, Binbin, Zhang, Zhansong, Sivaguru, Paramasivam, Zanoni, Giuseppe, Li, Shuang, Anderson, Edward A., Bi, Xihe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9314321/
https://www.ncbi.nlm.nih.gov/pubmed/35879307
http://dx.doi.org/10.1038/s41467-022-31976-z

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9314321/
https://www.ncbi.nlm.nih.gov/pubmed/35879307
http://dx.doi.org/10.1038/s41467-022-31976-z

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