The Varied Frustrated Lewis Pair Reactivity of the Germylene Phosphaketene (CH{(CMe)(2,6‐( i )Pr(2)C(6)H(3)N)}(2))GePCO

The germylene species (CH{(CMe)(2,6‐iPr(2)C(6)H(3)N)}(2))GePCO 1 is shown to react with the Lewis acids (E(C(6)F(5))(3) E=B, Al). Nonetheless, 1 participates in FLP chemistry with electron deficient alkynes or olefins, acting as an intramolecular FLP. In contrast, in the presence of B(C(6)F(5))(3) a...

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Detalles Bibliográficos
Autores principales: Wu, Yile, Zhao, Zhao, Chen, Ting, Tan, Jingjie, Qu, Zheng‐Wang, Grimme, Stefan, Zhao, Yufen, Stephan, Douglas W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9314608/
https://www.ncbi.nlm.nih.gov/pubmed/35262970
http://dx.doi.org/10.1002/chem.202200666

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9314608/
https://www.ncbi.nlm.nih.gov/pubmed/35262970
http://dx.doi.org/10.1002/chem.202200666

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