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Diphosphorus Release and Heterocumulene Oligomerisation by Nickel Complexes

The generation of diphosphorus molecules P(2) under mild conditions in solution is a useful strategy to generate diphosphines via [4+2] cycloadditions. We recently described the release of P(2) units from the nickel butterfly complex [{(IMes)Ni(CO)}(2)(μ(2),η(2):η(2)‐P(2))] (IMes=1,3‐bis(2,4,6‐trime...

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Detalles Bibliográficos
Autores principales: Hierlmeier, Gabriele, Wolf, Robert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9314841/
https://www.ncbi.nlm.nih.gov/pubmed/35915815
http://dx.doi.org/10.1002/ejic.202101057