Synthesis of Intramolecular P/Al‐Based Frustrated Lewis Pairs via Aluminum‐Tin‐Exchange and their Reactivity toward CO(2)

Frustrated Lewis pairs (FLPs) composed of acidic alane and basic phosphane functions, separated by a xanthene linker, can be prepared through the corresponding Me(3)Sn derivative and methyl aluminum compounds with elimination of Me(4)Sn. This way MeClAl‐, Cl(2)Al‐ and (C(6)F(5))(2)Al‐ moieties could...

Descripción completa

Detalles Bibliográficos
Autores principales: Federmann, Patrick, Müller, Robert, Beckmann, Fabian, Lau, Caroline, Cula, Beatrice, Kaupp, Martin, Limberg, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9314872/
https://www.ncbi.nlm.nih.gov/pubmed/35213074
http://dx.doi.org/10.1002/chem.202200404

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9314872/
https://www.ncbi.nlm.nih.gov/pubmed/35213074
http://dx.doi.org/10.1002/chem.202200404

Ejemplares similares