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Synthesis of Intramolecular P/Al‐Based Frustrated Lewis Pairs via Aluminum‐Tin‐Exchange and their Reactivity toward CO(2)

Frustrated Lewis pairs (FLPs) composed of acidic alane and basic phosphane functions, separated by a xanthene linker, can be prepared through the corresponding Me(3)Sn derivative and methyl aluminum compounds with elimination of Me(4)Sn. This way MeClAl‐, Cl(2)Al‐ and (C(6)F(5))(2)Al‐ moieties could...

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Detalles Bibliográficos
Autores principales:	Federmann, Patrick, Müller, Robert, Beckmann, Fabian, Lau, Caroline, Cula, Beatrice, Kaupp, Martin, Limberg, Christian
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9314872/ https://www.ncbi.nlm.nih.gov/pubmed/35213074 http://dx.doi.org/10.1002/chem.202200404

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