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A real space picture of the role of steric effects in S(N)2 reactions

Within substitution reactions, the Bimolecular Nucleophilic Substitution (S(N)2) reaction mechanism is one of the most frequently found and studied ones. Among other factors, the easiness of the S(N)2 pathway is classically considered to be determined by steric hindrance. However, the diffuse nature...

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Detalles Bibliográficos
Autores principales: Gallegos, Miguel, Costales, Aurora, Martín Pendás, Ángel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley & Sons, Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9314895/
https://www.ncbi.nlm.nih.gov/pubmed/35277994
http://dx.doi.org/10.1002/jcc.26834