Enantio‐ and Diastereoselective Copper‐Catalyzed Allylboration of Alkynes with Allylic gem‐Dichlorides

Allylic gem‐dichlorides are shown to be efficient substrates for catalytic asymmetric allylboration of alkynes. The method employs a chiral NHC−Cu catalyst capable of generating in a single step chiral skipped dienes bearing a Z‐alkenyl chloride, a trisubstituted E‐alkenyl boronate and a bis‐allylic...

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Detalles Bibliográficos
Autores principales: Chaves‐Pouso, Andrea, Álvarez‐Constantino, Andrés M., Fañanás‐Mastral, Martín
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9314970/
https://www.ncbi.nlm.nih.gov/pubmed/35263483
http://dx.doi.org/10.1002/anie.202117696

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9314970/
https://www.ncbi.nlm.nih.gov/pubmed/35263483
http://dx.doi.org/10.1002/anie.202117696

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