Synthesis of Molecular Phenylcalcium Derivatives: Application to the Formation of Biaryls

Hydrocarbon‐soluble β‐diketiminato phenylcalcium derivatives, which display various modes of Ca−μ(2)‐Ph−Ca bridging, are accessible from reactions of Ph(2)Hg and [(BDI)CaH](2). Although the resultant compounds are inert toward the C−H bonds of benzene, they yield selective and uncatalyzed biaryl for...

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Detalles Bibliográficos
Autores principales: Pearce, Kyle G., Dinoi, Chiara, Hill, Michael S., Mahon, Mary F., Maron, Laurent, Schwamm, Ryan S., Wilson, Andrew S. S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9315018/
https://www.ncbi.nlm.nih.gov/pubmed/35212128
http://dx.doi.org/10.1002/anie.202200305

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9315018/
https://www.ncbi.nlm.nih.gov/pubmed/35212128
http://dx.doi.org/10.1002/anie.202200305

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