Synthesis of Molecular Phenylcalcium Derivatives: Application to the Formation of Biaryls

Hydrocarbon‐soluble β‐diketiminato phenylcalcium derivatives, which display various modes of Ca−μ(2)‐Ph−Ca bridging, are accessible from reactions of Ph(2)Hg and [(BDI)CaH](2). Although the resultant compounds are inert toward the C−H bonds of benzene, they yield selective and uncatalyzed biaryl for...

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Detalles Bibliográficos
Autores principales: Pearce, Kyle G., Dinoi, Chiara, Hill, Michael S., Mahon, Mary F., Maron, Laurent, Schwamm, Ryan S., Wilson, Andrew S. S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9315018/
https://www.ncbi.nlm.nih.gov/pubmed/35212128
http://dx.doi.org/10.1002/anie.202200305
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author Pearce, Kyle G.
Dinoi, Chiara
Hill, Michael S.
Mahon, Mary F.
Maron, Laurent
Schwamm, Ryan S.
Wilson, Andrew S. S.
author_facet Pearce, Kyle G.
Dinoi, Chiara
Hill, Michael S.
Mahon, Mary F.
Maron, Laurent
Schwamm, Ryan S.
Wilson, Andrew S. S.
author_sort Pearce, Kyle G.
collection PubMed
description Hydrocarbon‐soluble β‐diketiminato phenylcalcium derivatives, which display various modes of Ca−μ(2)‐Ph−Ca bridging, are accessible from reactions of Ph(2)Hg and [(BDI)CaH](2). Although the resultant compounds are inert toward the C−H bonds of benzene, they yield selective and uncatalyzed biaryl formation when reacted with readily available aryl bromides.
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spelling pubmed-93150182022-07-30 Synthesis of Molecular Phenylcalcium Derivatives: Application to the Formation of Biaryls Pearce, Kyle G. Dinoi, Chiara Hill, Michael S. Mahon, Mary F. Maron, Laurent Schwamm, Ryan S. Wilson, Andrew S. S. Angew Chem Int Ed Engl Communications Hydrocarbon‐soluble β‐diketiminato phenylcalcium derivatives, which display various modes of Ca−μ(2)‐Ph−Ca bridging, are accessible from reactions of Ph(2)Hg and [(BDI)CaH](2). Although the resultant compounds are inert toward the C−H bonds of benzene, they yield selective and uncatalyzed biaryl formation when reacted with readily available aryl bromides. John Wiley and Sons Inc. 2022-03-07 2022-04-25 /pmc/articles/PMC9315018/ /pubmed/35212128 http://dx.doi.org/10.1002/anie.202200305 Text en © 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH https://creativecommons.org/licenses/by/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Pearce, Kyle G.
Dinoi, Chiara
Hill, Michael S.
Mahon, Mary F.
Maron, Laurent
Schwamm, Ryan S.
Wilson, Andrew S. S.
Synthesis of Molecular Phenylcalcium Derivatives: Application to the Formation of Biaryls
title Synthesis of Molecular Phenylcalcium Derivatives: Application to the Formation of Biaryls
title_full Synthesis of Molecular Phenylcalcium Derivatives: Application to the Formation of Biaryls
title_fullStr Synthesis of Molecular Phenylcalcium Derivatives: Application to the Formation of Biaryls
title_full_unstemmed Synthesis of Molecular Phenylcalcium Derivatives: Application to the Formation of Biaryls
title_short Synthesis of Molecular Phenylcalcium Derivatives: Application to the Formation of Biaryls
title_sort synthesis of molecular phenylcalcium derivatives: application to the formation of biaryls
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9315018/
https://www.ncbi.nlm.nih.gov/pubmed/35212128
http://dx.doi.org/10.1002/anie.202200305
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