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Synthesis of Molecular Phenylcalcium Derivatives: Application to the Formation of Biaryls
Hydrocarbon‐soluble β‐diketiminato phenylcalcium derivatives, which display various modes of Ca−μ(2)‐Ph−Ca bridging, are accessible from reactions of Ph(2)Hg and [(BDI)CaH](2). Although the resultant compounds are inert toward the C−H bonds of benzene, they yield selective and uncatalyzed biaryl for...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9315018/ https://www.ncbi.nlm.nih.gov/pubmed/35212128 http://dx.doi.org/10.1002/anie.202200305 |