Exploring the Reactivity of B‐Connected Carboranylphosphines in Frustrated Lewis Pair Chemistry: A New Frame for a Classic System

The primary phosphines MesPH(2) and tBuPH(2) react with 9‐iodo‐m‐carborane yielding B9‐connected secondary carboranylphosphines 1,7‐H(2)C(2)B(10)H(9)‐9‐PHR (R=2,4,6‐Me(3)C(6)H(2) (Mes; 1  a), tBu (1  b)). Addition of tris(pentafluorophenyl)borane (BCF) to 1  a, b resulted in the zwitterionic compoun...

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Detalles Bibliográficos
Autores principales: Schulz, Jan, Sárosi, Menyhárt B., Hey‐Hawkins, Evamarie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9320892/
https://www.ncbi.nlm.nih.gov/pubmed/35472172
http://dx.doi.org/10.1002/chem.202200531

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9320892/
https://www.ncbi.nlm.nih.gov/pubmed/35472172
http://dx.doi.org/10.1002/chem.202200531

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