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Exploring the Reactivity of B‐Connected Carboranylphosphines in Frustrated Lewis Pair Chemistry: A New Frame for a Classic System
The primary phosphines MesPH(2) and tBuPH(2) react with 9‐iodo‐m‐carborane yielding B9‐connected secondary carboranylphosphines 1,7‐H(2)C(2)B(10)H(9)‐9‐PHR (R=2,4,6‐Me(3)C(6)H(2) (Mes; 1 a), tBu (1 b)). Addition of tris(pentafluorophenyl)borane (BCF) to 1 a, b resulted in the zwitterionic compoun...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9320892/ https://www.ncbi.nlm.nih.gov/pubmed/35472172 http://dx.doi.org/10.1002/chem.202200531 |