Synthesis of Genuine Germenyl Lithiums and the First Persistent Germenyl Radicals

The first isolated genuine germenyl lithiums (R(3)Si)(1‐Ad)C=Ge(SiMetBu(2))(Li⋅2 L) (R(3)Si=tBu(2)MeSi, L=THF (1  a), or L=12‐crown‐4 (1  b) and R(3)Si=tBuMe(2)Si, L=THF (2  a), or L=12‐crown‐4 (2  b)), were synthesized by reaction of the corresponding acyl germanes 3 and 4, respectively, with tBu(2...

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Detalles Bibliográficos
Autores principales: Goldshtein, Yulia, Glagovsky, Yuri, Tumanskii, Boris, Fridman, Natalia, Bravo‐Zhivotovskii, Dmitry, Apeloig, Yitzhak
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9320928/
https://www.ncbi.nlm.nih.gov/pubmed/35438228
http://dx.doi.org/10.1002/anie.202202452

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9320928/
https://www.ncbi.nlm.nih.gov/pubmed/35438228
http://dx.doi.org/10.1002/anie.202202452

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