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Synthesis of Genuine Germenyl Lithiums and the First Persistent Germenyl Radicals
The first isolated genuine germenyl lithiums (R(3)Si)(1‐Ad)C=Ge(SiMetBu(2))(Li⋅2 L) (R(3)Si=tBu(2)MeSi, L=THF (1 a), or L=12‐crown‐4 (1 b) and R(3)Si=tBuMe(2)Si, L=THF (2 a), or L=12‐crown‐4 (2 b)), were synthesized by reaction of the corresponding acyl germanes 3 and 4, respectively, with tBu(2...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9320928/ https://www.ncbi.nlm.nih.gov/pubmed/35438228 http://dx.doi.org/10.1002/anie.202202452 |