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Selective Labeling of Peptides with o‐Carboranes via Manganese(I)‐Catalyzed C−H Activation
A robust method for the selective labeling of peptides via manganese(I) catalysis was devised to achieve the C‐2 alkenylation of tryptophan containing peptides with 1‐ethynyl‐o‐carboranes. The manganese‐catalyzed C−H activation was accomplished with high catalytic efficiency, and featured low toxici...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9320968/ https://www.ncbi.nlm.nih.gov/pubmed/35420234 http://dx.doi.org/10.1002/chem.202200811 |