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Selective Labeling of Peptides with o‐Carboranes via Manganese(I)‐Catalyzed C−H Activation

A robust method for the selective labeling of peptides via manganese(I) catalysis was devised to achieve the C‐2 alkenylation of tryptophan containing peptides with 1‐ethynyl‐o‐carboranes. The manganese‐catalyzed C−H activation was accomplished with high catalytic efficiency, and featured low toxici...

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Detalles Bibliográficos
Autores principales:	Jei, Becky Bongsuiru, Yang, Long, Ackermann, Lutz
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9320968/ https://www.ncbi.nlm.nih.gov/pubmed/35420234 http://dx.doi.org/10.1002/chem.202200811

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