Decarbonylative Transfer Hydrochlorination of Alkenes and Alkynes Based on a B(C(6)F(5))(3)‐Initiated Grob Fragmentation

Readily available cyclohexa‐2,5‐dien‐1‐ylcarbonyl chloride derivatives are introduced as bench‐stable HCl surrogates for transfer hydrochlorination of terminal and internal alkenes as well as selected alkynes. The stepwise Grob fragmentation of those acyl chlorides into chloride, carbon monoxide, a...

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Detalles Bibliográficos
Autores principales: Xie, Kaixue, Oestreich, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9321001/
https://www.ncbi.nlm.nih.gov/pubmed/35325506
http://dx.doi.org/10.1002/anie.202203692

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9321001/
https://www.ncbi.nlm.nih.gov/pubmed/35325506
http://dx.doi.org/10.1002/anie.202203692

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