Cargando…

Neighboring Group Participation of Benzoyl Protecting Groups in C3‐ and C6‐Fluorinated Glucose

Fluorination is a potent method to modulate chemical properties of glycans. Here, we study how C3‐ and C6‐fluorination of glucosyl building blocks influence the structure of the intermediate of the glycosylation reaction, the glycosyl cation. Using a combination of gas‐phase infrared spectroscopy an...

Descripción completa

Detalles Bibliográficos
Autores principales: Greis, Kim, Kirschbaum, Carla, Fittolani, Giulio, Mucha, Eike, Chang, Rayoon, von Helden, Gert, Meijer, Gerard, Delbianco, Martina, Seeberger, Peter H., Pagel, Kevin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9321577/
https://www.ncbi.nlm.nih.gov/pubmed/35915640
http://dx.doi.org/10.1002/ejoc.202200255