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Neighboring Group Participation of Benzoyl Protecting Groups in C3‐ and C6‐Fluorinated Glucose
Fluorination is a potent method to modulate chemical properties of glycans. Here, we study how C3‐ and C6‐fluorination of glucosyl building blocks influence the structure of the intermediate of the glycosylation reaction, the glycosyl cation. Using a combination of gas‐phase infrared spectroscopy an...
Autores principales: | Greis, Kim, Kirschbaum, Carla, Fittolani, Giulio, Mucha, Eike, Chang, Rayoon, von Helden, Gert, Meijer, Gerard, Delbianco, Martina, Seeberger, Peter H., Pagel, Kevin |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9321577/ https://www.ncbi.nlm.nih.gov/pubmed/35915640 http://dx.doi.org/10.1002/ejoc.202200255 |
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