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Low‐Temperature Isolation of a Labile Silylated Hydrazinium‐yl Radical Cation, [(Me(3)Si)(2)N−N(H)SiMe(3)](.+)
The oxidation of silylated hydrazine, (Me(3)Si)(2)N−N(H)SiMe(3), with silver salts led to the formation of a highly labile hydrazinium‐yl radical cation, [(Me(3)Si)(2)N−N(H)SiMe(3)](.+), at very low temperatures (decomposition > −40 °C). EPR, NMR, DFT and Raman studies revealed the formation of a...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9321631/ https://www.ncbi.nlm.nih.gov/pubmed/35404528 http://dx.doi.org/10.1002/chem.202200854 |