Acenaphthenoannulation Induced by the Dual Lewis Acidity of Alumina

We have discovered a dual (i. e., soft and hard) Lewis acidity of alumina that enables rapid one‐pot π‐extension through the activation of terminal alkynes followed by C−F activation. The tandem reaction introduces an acenaphthene fragment – an essential moiety of geodesic polyarenes. This reaction...

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Detalles Bibliográficos
Autores principales: Akhmetov, Vladimir, Feofanov, Mikhail, Ruppenstein, Cordula, Lange, Josefine, Sharapa, Dmitry, Krstić, Marjan, Hampel, Frank, Kataev, Evgeny A., Amsharov, Konstantin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9321853/
https://www.ncbi.nlm.nih.gov/pubmed/35313382
http://dx.doi.org/10.1002/chem.202200584

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9321853/
https://www.ncbi.nlm.nih.gov/pubmed/35313382
http://dx.doi.org/10.1002/chem.202200584

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