An Allyl Uranium(IV) Sandwich Complex: Are ϕ Bonding Interactions Possible?

A method to explore head‐to‐head ϕ back‐bonding from uranium f‐orbitals into allyl π* orbitals has been pursued. Anionic allyl groups were coordinated to uranium with tethered anilide ligands, then the products were investigated by using NMR spectroscopy, single‐crystal XRD, and theoretical methods....

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Detalles Bibliográficos
Autores principales: Popov, Ivan A., Billow, Brennan S., Carpenter, Stephanie H., Batista, Enrique R., Boncella, James M., Tondreau, Aaron M., Yang, Ping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9322041/
https://www.ncbi.nlm.nih.gov/pubmed/35286723
http://dx.doi.org/10.1002/chem.202200114

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9322041/
https://www.ncbi.nlm.nih.gov/pubmed/35286723
http://dx.doi.org/10.1002/chem.202200114

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