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Dismutation of Tricyanoboryllead Compounds: The Homoleptic Tetrakis(tricyanoboryl)plumbate Tetraanion

A series of unprecedently air‐stable (tricyanoboryl)plumbate anions was obtained by the reaction of the boron‐centered nucleophile B(CN)(3) (2−) with triorganyllead halides. Salts of the anions [R(3)PbB(CN)(3)](−) (R=Ph, Et) were isolated and found to be stable in air at room temperature. In the cas...

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Detalles Bibliográficos
Autores principales: Häring, Mathias, Kerpen, Christoph, Ribbeck, Tatjana, Hennig, Philipp T., Bertermann, Rüdiger, Ignat'ev, Nikolai V., Finze, Maik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9322310/
https://www.ncbi.nlm.nih.gov/pubmed/35266266
http://dx.doi.org/10.1002/anie.202202882