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A Mesoionic Diselenolene Anion and the Corresponding Radical Dianion

Dichalcogenolenes are archetypal redox non‐innocent ligands with numerous applications. Herein, a diselenolene ligand with fundamentally different electronic properties is described. A mesoionic diselenolene was prepared by selenation of a C2‐protected imidazolium salt. This ligand is diamagnetic, w...

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Detalles Bibliográficos
Autores principales: Dong, Zhaowen, Sienkiewicz, Andrzej, Suleymanov, Abdusalom A., Berton, Cesare, Fadaei‐Tirani, Farzaneh, Scopelliti, Rosario, Severin, Kay
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9322424/
https://www.ncbi.nlm.nih.gov/pubmed/35388932
http://dx.doi.org/10.1002/chem.202200893