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An Anionic Dinuclear Ruthenium Dihydrogen Complex of Relevance for Alkyne gem‐Hydrogenation

During an investigation into the fate of ruthenium precatalysts used for light‐driven alkyne gem‐hydrogenation reactions with formation of Grubbs‐type ruthenium catalysts, it was found that the reaction of [(IPr)(η(6)‐cymene)RuCl(2)] with H(2) under UV‐irradiation affords an anionic dinuclear σ‐dihy...

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Detalles Bibliográficos
Autores principales: Biberger, Tobias, Nöthling, Nils, Leutzsch, Markus, Gordon, Christopher P., Copéret, Christophe, Fürstner, Alois
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9322539/
https://www.ncbi.nlm.nih.gov/pubmed/35363926
http://dx.doi.org/10.1002/anie.202201311