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An Anionic Dinuclear Ruthenium Dihydrogen Complex of Relevance for Alkyne gem‐Hydrogenation
During an investigation into the fate of ruthenium precatalysts used for light‐driven alkyne gem‐hydrogenation reactions with formation of Grubbs‐type ruthenium catalysts, it was found that the reaction of [(IPr)(η(6)‐cymene)RuCl(2)] with H(2) under UV‐irradiation affords an anionic dinuclear σ‐dihy...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9322539/ https://www.ncbi.nlm.nih.gov/pubmed/35363926 http://dx.doi.org/10.1002/anie.202201311 |