Reactivity of Xantphos‐Type Rhodium Complexes Towards SF(4): SF(3) Versus SF(2) Complex Generation

S−F‐bond activation of sulfur tetrafluoride at [Rh(Cl)(( tBu)xanPOP)] (1; ( tBu)xanPOP=9,9‐dimethyl‐4,5‐bis‐(di‐tert‐butylphosphino)‐xanthene) led to the formation of the cationic complex [Rh(F)(Cl)(SF(2))(( tBu)xanPOP)][SF(5)] (2 a) together with trans‐[Rh(Cl)(F)(2)(( tBu)xanPOP)] (3) and cis‐[Rh(C...

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Detalles Bibliográficos
Autores principales: Wozniak, Martin, Sander, Stefan, Cula, Beatrice, Ahrens, Mike, Braun, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9322540/
https://www.ncbi.nlm.nih.gov/pubmed/35420718
http://dx.doi.org/10.1002/chem.202200626

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9322540/
https://www.ncbi.nlm.nih.gov/pubmed/35420718
http://dx.doi.org/10.1002/chem.202200626

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