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Reactivity of Xantphos‐Type Rhodium Complexes Towards SF(4): SF(3) Versus SF(2) Complex Generation
S−F‐bond activation of sulfur tetrafluoride at [Rh(Cl)(( tBu)xanPOP)] (1; ( tBu)xanPOP=9,9‐dimethyl‐4,5‐bis‐(di‐tert‐butylphosphino)‐xanthene) led to the formation of the cationic complex [Rh(F)(Cl)(SF(2))(( tBu)xanPOP)][SF(5)] (2 a) together with trans‐[Rh(Cl)(F)(2)(( tBu)xanPOP)] (3) and cis‐[Rh(C...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9322540/ https://www.ncbi.nlm.nih.gov/pubmed/35420718 http://dx.doi.org/10.1002/chem.202200626 |