Radical Reactivity of the Biradical [⋅P(μ‐NTer)(2)P⋅] and Isolation of a Persistent Phosphorus‐Cantered Monoradical [⋅P(μ‐NTer)(2)P‐Et]

The activation of C−Br bonds in various bromoalkanes by the biradical [⋅P(μ‐NTer)(2)P⋅] (1) (Ter=2,6‐bis‐(2,4,6‐trimethylphenyl)‐phenyl) is reported, yielding trans‐addition products of the type [Br−P(μ‐NTer)(2)P−R] (2), so‐called 1,3‐substituted cyclo‐1,3‐diphospha‐2,4‐diazanes. This addition react...

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Detalles Bibliográficos
Autores principales: Rosenboom, Jan, Chojetzki, Lukas, Suhrbier, Tim, Rabeah, Jabor, Villinger, Alexander, Wustrack, Ronald, Bresien, Jonas, Schulz, Axel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9322606/
https://www.ncbi.nlm.nih.gov/pubmed/35445770
http://dx.doi.org/10.1002/chem.202200624

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9322606/
https://www.ncbi.nlm.nih.gov/pubmed/35445770
http://dx.doi.org/10.1002/chem.202200624

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