A Terphenyl Supported Dioxophosphorane Dimer: the Light Congener of Lawesson's and Woollins’ Reagents

Thermolysis of a 1,3‐dioxa‐2‐phospholane supported by the terphenyl ligand Ar(iPr4) (Ar(iPr4)=[C(6)H(3)‐2,6‐(C(6)H(3)‐2,6‐iPr(2))]) at 150 °C gives [Ar(iPr4)PO(2)](2) via loss of ethene. [Ar(iPr4)PO(2)](2) was characterised by X‐ray crystallography and NMR spectroscopy; it contains a 4‐membered P−O−...

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Detalles Bibliográficos
Autores principales: English, Laura E., Pajak, Aleksandra, McMullin, Claire L., Lowe, John P., Mahon, Mary F., Liptrot, David J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9322665/
https://www.ncbi.nlm.nih.gov/pubmed/35320601
http://dx.doi.org/10.1002/chem.202200376

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9322665/
https://www.ncbi.nlm.nih.gov/pubmed/35320601
http://dx.doi.org/10.1002/chem.202200376

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