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Enantioselective Cytotoxicity of Chiral Diphosphine Ruthenium(II) Complexes Against Cancer Cells

The chiral cationic complex [Ru(η(1)‐OAc)(CO)((R,R)‐Skewphos)(phen)]OAc (2 ( R )), isolated from reaction of [Ru(η(1)‐OAc)(η(2)‐OAc)(R,R)‐Skewphos)(CO)] (1 ( R )) with phen, reacts with NaOPiv and KSAc affording [RuX(CO)((R,R)‐Skewphos)(phen)]Y (X=Y=OPiv 3 ( R ); X=SAc, Y=OAc 4 ( R )). The correspon...

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Detalles Bibliográficos
Autores principales: Lovison, Denise, Alessi, Dario, Allegri, Lorenzo, Baldan, Federica, Ballico, Maurizio, Damante, Giuseppe, Galasso, Marilisa, Guardavaccaro, Daniele, Ruggieri, Silvia, Melchior, Andrea, Veclani, Daniele, Nardon, Chiara, Baratta, Walter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9322675/
https://www.ncbi.nlm.nih.gov/pubmed/35394095
http://dx.doi.org/10.1002/chem.202200200