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Gold(I) α‐Trifluoromethyl Carbenes: Synthesis, Characterization and Reactivity Studies
Aryl trifluoromethyl diazomethanes 2‐R (R=Ph, OMe, CF(3)) are readily decomposed by the (o‐carboranyl)diphosphine gold(I) complex 1. The resulting α‐CF(3) substituted carbene complexes 3‐R have been characterized by multi‐nuclear NMR spectroscopy as well as X‐ray crystallography (for 3‐Ph). The bond...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9323441/ https://www.ncbi.nlm.nih.gov/pubmed/35466483 http://dx.doi.org/10.1002/anie.202204781 |