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Gold(I) α‐Trifluoromethyl Carbenes: Synthesis, Characterization and Reactivity Studies

Aryl trifluoromethyl diazomethanes 2‐R (R=Ph, OMe, CF(3)) are readily decomposed by the (o‐carboranyl)diphosphine gold(I) complex 1. The resulting α‐CF(3) substituted carbene complexes 3‐R have been characterized by multi‐nuclear NMR spectroscopy as well as X‐ray crystallography (for 3‐Ph). The bond...

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Detalles Bibliográficos
Autores principales:	Rigoulet, Mathilde, Vesseur, David, Miqueu, Karinne, Bourissou, Didier
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9323441/ https://www.ncbi.nlm.nih.gov/pubmed/35466483 http://dx.doi.org/10.1002/anie.202204781

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