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Copper‐Catalyzed Monooxygenation of Phenols: Evidence for a Mononuclear Reaction Mechanism

The Cu(I) salts [Cu(CH(3)CN)(4)]PF and [Cu(oDFB)(2)]PF with the very weakly coordinating anion Al(OC(CF(3))(3))(4) (−) (PF) as well as [Cu(NEt(3))(2)]PF comprising the unique, linear bis‐triethylamine complex [Cu(NEt(3))(2)](+) were synthesized and examined as catalysts for the conversion of monophe...

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Detalles Bibliográficos
Autores principales: Schneider, Rebecca, Engesser, Tobias A., Näther, Christian, Krossing, Ingo, Tuczek, Felix
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9323449/
https://www.ncbi.nlm.nih.gov/pubmed/35344617
http://dx.doi.org/10.1002/anie.202202562