Tuning the Stereoselectivity of an Intramolecular Aldol Reaction by Precisely Modifying a Metal‐Organic Framework Catalyst

We report the catalysis of an enantioselective, intramolecular aldol reaction accelerated by an organocatalyst embedded in a series of multicomponent metal‐organic frameworks. By precisely programming the pore microenvironment around the site of catalysis, we show how important features of an intram...

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Detalles Bibliográficos
Autores principales: Cornelio, Joel, Telfer, Shane G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9323468/
https://www.ncbi.nlm.nih.gov/pubmed/35466580
http://dx.doi.org/10.1002/asia.202200243

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9323468/
https://www.ncbi.nlm.nih.gov/pubmed/35466580
http://dx.doi.org/10.1002/asia.202200243

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