Mesoionic Dithiolates (MIDts) Derived from 1,3‐Imidazole‐Based Anionic Dicarbenes (ADCs)

Mesoionic dithiolates [(MIDt(Ar))Li(LiBr)(2)(THF)(3)] (MIDt(Ar)={SC(NDipp)}(2)CAr; Dipp=2,6‐iPr(2)C(6)H(3); Ar=Ph 3 a, 3‐MeC(6)H(4) (3‐Tol) 3 b, 4‐Me(2)NC(6)H(4) (DMP) 3 c) and [(MIDt(Ph))Li(THF)(2)] (4) are readily accessible (in≥90 % yields) as crystalline solids on treatments of anionic dicarbene...

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Detalles Bibliográficos
Autores principales: Ebeler, Falk, Vishnevskiy, Yury V., Neumann, Beate, Stammler, Hans‐Georg, Ghadwal, Rajendra S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9323478/
https://www.ncbi.nlm.nih.gov/pubmed/35363912
http://dx.doi.org/10.1002/chem.202200739

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9323478/
https://www.ncbi.nlm.nih.gov/pubmed/35363912
http://dx.doi.org/10.1002/chem.202200739

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