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Mesoionic Dithiolates (MIDts) Derived from 1,3‐Imidazole‐Based Anionic Dicarbenes (ADCs)
Mesoionic dithiolates [(MIDt(Ar))Li(LiBr)(2)(THF)(3)] (MIDt(Ar)={SC(NDipp)}(2)CAr; Dipp=2,6‐iPr(2)C(6)H(3); Ar=Ph 3 a, 3‐MeC(6)H(4) (3‐Tol) 3 b, 4‐Me(2)NC(6)H(4) (DMP) 3 c) and [(MIDt(Ph))Li(THF)(2)] (4) are readily accessible (in≥90 % yields) as crystalline solids on treatments of anionic dicarbene...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9323478/ https://www.ncbi.nlm.nih.gov/pubmed/35363912 http://dx.doi.org/10.1002/chem.202200739 |