Cooperative Palladium/Isothiourea Catalyzed Enantioselective Formal (3+2) Cycloaddition of Vinylcyclopropanes and α,β‐Unsaturated Esters

A protocol for the enantioselective synthesis of substituted vinylcyclopentanes has been realised using cooperative palladium and isothiourea catalysis. Treatment of vinylcyclopropanes with Pd(PPh(3))(4) generates a zwitterionic π‐allyl palladium intermediate that intercepts a catalytically generate...

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Detalles Bibliográficos
Autores principales: Bitai, Jacqueline, Nimmo, Alastair J., Slawin, Alexandra M. Z., Smith, Andrew D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9324207/
https://www.ncbi.nlm.nih.gov/pubmed/35389553
http://dx.doi.org/10.1002/anie.202202621

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9324207/
https://www.ncbi.nlm.nih.gov/pubmed/35389553
http://dx.doi.org/10.1002/anie.202202621

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