Stereoinvertive Nucleophilic Substitution at Quaternary Carbon Stereocenters of Cyclopropyl Ketones and Ethers

A highly regio‐ and diastereoselective nucleophilic substitution at the quaternary carbon stereocenter of cyclopropyl ketones and cyclopropyl carbinol derivatives using TMSBr, DMPSCl and TMSN(3) as nucleophiles has been developed. A variety of acyclic tertiary alkyl bromides, chlorides and azides we...

Descripción completa

Detalles Bibliográficos
Autores principales: Chen, Xu, Marek, Ilan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9324837/
https://www.ncbi.nlm.nih.gov/pubmed/35471589
http://dx.doi.org/10.1002/anie.202203673

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9324837/
https://www.ncbi.nlm.nih.gov/pubmed/35471589
http://dx.doi.org/10.1002/anie.202203673

Ejemplares similares