The Non‐Ancillary Nature of Trimethylsilylamide Substituents in Boranes and Borinium Cations

The known boranes (R(Me(3)Si)N)(2)BF (R=Me(3)Si 1 , tBu 2, C(6)F(5) 3, o‐tol 4, Mes 5, Dipp 6) and borinium salts (R(Me(3)Si)N)(2)B][B(C(6)F(5))(4)] (R=Me(3)Si 7, tBu 8) are prepared and fully characterized. Compound 7 is shown to react with phosphines to generate [R(3)PSiMe(3)](+) and [R(3)PH](+) (...

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Detalles Bibliográficos
Autores principales: Major, Christopher J., Qu, Zheng‐Wang, Grimme, Stefan, Stephan, Douglas W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9324859/
https://www.ncbi.nlm.nih.gov/pubmed/35262980
http://dx.doi.org/10.1002/chem.202200698

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9324859/
https://www.ncbi.nlm.nih.gov/pubmed/35262980
http://dx.doi.org/10.1002/chem.202200698

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