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The Non‐Ancillary Nature of Trimethylsilylamide Substituents in Boranes and Borinium Cations
The known boranes (R(Me(3)Si)N)(2)BF (R=Me(3)Si 1 , tBu 2, C(6)F(5) 3, o‐tol 4, Mes 5, Dipp 6) and borinium salts (R(Me(3)Si)N)(2)B][B(C(6)F(5))(4)] (R=Me(3)Si 7, tBu 8) are prepared and fully characterized. Compound 7 is shown to react with phosphines to generate [R(3)PSiMe(3)](+) and [R(3)PH](+) (...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9324859/ https://www.ncbi.nlm.nih.gov/pubmed/35262980 http://dx.doi.org/10.1002/chem.202200698 |