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Palladium‐Catalyzed Tandem Cycloisomerization/Cross‐Coupling of Carbonyl‐ and Imine‐Tethered Alkylidenecyclopropanes

Pd(0) catalysts featuring phosphorus‐based monodentate ligands can detour the reactivity of carbonyl‐tethered alkylidenecyclopropanes (ACPs) from standard (3+2) cycloadditions towards tandem cycloisomerization/cross‐coupling processes. This new reactivity lies on the formation of key π‐allyl oxapall...

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Detalles Bibliográficos
Autores principales: Verdugo, Felipe, Rodiño, Ricardo, Calvelo, Martín, Mascareñas, José Luis, López, Fernando
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9324954/
https://www.ncbi.nlm.nih.gov/pubmed/35348273
http://dx.doi.org/10.1002/anie.202202295